Alkylcarbamylmethylated aminotriazine crosslinking agents and curable compositions containing the same

ABSTRACT

Novel alkylcarbamylmethyl aminotriazines self-cure and also function as crosslinkers for compounds containing active hydrogen groups. When the active hydrogen-containing compounds are hydroxylated polymers, coatings are provided with exceptional resistance to detergent and salt-spray exposure and improved abrasion resistance. The novel aminotriazines also can be combined with fillers as binders which when cured provide shaped articles of manufacture, such as insulation and foundry core molds.

This is a divisional of co-pending application Ser. No. 07/120,285, filed on Nov. 12, 1987, now U.S. Pat. No. 5,006,653 which is a divisional of patent applicaiton Ser. No. 06/864,627, filed May 16, 1986, and now U.S. Pat. No. 4,710,542.

The present invention relates to curing agents, to curable compositions and to methods of making and using them. More particularly, the present invention relates to novel curing agents comprising alkylcarbamylmethylaminotriazines and to curable compositions comprising an active hydrogen-containing material, a novel alkylcarbamylmethylaminotriazine and a cure catalyst. Coatings cured from the compositions have exceptional resistance to detergent and salt spray exposure, making them well adapted for use in powder coatings, coil coatings and can coatings. The new compositions can be used with filler to provide shaped articles of manufacture with superior properties.

BACKGROUND OF THE INVENTION

Curable compositions containing aminotriazine compounds are known in the art. As is shown in Koral et al., U.S. Pat. No. 3,661,819, for example, a preferred family of aminotriazine curing agents comprises (i) a triaminotriazine compound of the formula: ##STR1## which will be depicted hereinafter as C₃ N₆ (CH₂ OR)₆ ; or (ii) a benzoguanamine compound of the formula: ##STR2## which will be depicted hereinafter as C₃ N₅ (C₆ H₅) (CH₂ OR)₄ wherein R is hydrogen or alkyl of from 1 to 12 carbon atoms. It is also known to use oligomers of such compounds, which are low molecular weight condensation products containing for example two, three or four triazine rings, joined by --CH₂ OCH₂ --linkages, as well as mixtures of any of the foregoing. These are used to cure active hydrogen-containing materials, especially polymers which contain carboxyl groups, alcoholic hydroxy groups, amide groups and groups convertible to such groups, such as methylol groups. When such curable compositions are applied to substrates as coatings and then cured, excellent hardness, impact resistance, light stability and solvent resistance is imparted to the articles. The compositions can also be formulated with fillers and/or reinforcements such as particulate and fibrous mineral and organic materials, such as cellulose, wood, glass, graphite, textiles, silica, asbestos, wollerstonite, and the like to produce insulation, foundry molds and the like which have superior properties and show a reduced tendency to emit formaldehyde during use.

As is described in German Patent OL 2,005,693 (1971) (Chemical Abstracts 76:P 34864 a (1972)), when triaminotriazines of the general formula (i) above are reacted with arylurethanes, such as phenyl urethane, there are produced reaction products of the typical formula C₃ N₆ (CH₂ --NH--COOC₆ H₅)₆, and when these are reacted with polymers containing hydroxyl groups such as acrylics and polyesters, crosslinking occurs with the development of colorless, very hard films, which remain colorless even when the baking time is increased tenfold, to five hours at 100° C. However, subsequent experiments have shown that such coatings, like those crosslinked with the triazines of formulae (i) and (ii) above, are somewhat deficient in detergent resistance, salt spray resistance and adhesion. They also are produced with the liberation of phenol, which causes health and disposal problems, and is economically wasteful.

It has now been discovered that if aminotriazines of general formulae (i) and (ii) are reacted with alkylurethanes (which are well known to be less reactive than the aryl carbamates used in the above-mentioned German Patent), derivatives are formed which are also reactive to crosslink active hydrogen-containing polymers, but the new coatings which are formed have much improved properties (detergent, salt spray, adhesion, color retention) over those of the prior art, particularly the aryl-substituted derivatives of OL 2,005,693.

Although it is known, e.g., from Amin et al., Indian J. Chem., 14B, 139-140 (1976), to prepare both aryl and alkyl carbamylmethylated melamines, by the reaction of trimethylolmelamine with n-hexyl carbamate, only the mono-substituted product was produced, and this would not be capable of acting as a crosslinker to introduce two or more urethane groups. Such groups are now believed to be essential to secure all of the advantages of the present invention.

Thus the present invention differs from the state of the art by providing aminotriazine derivatives containing at least two alkylcarbamylmethyl groups and then using them as crosslinkers for active hydrogen-containing materials to provide coatings with exceptional resistance, for example, to detergent and salt-spray exposure, and improved light stability.

SUMMARY OF THE INVENTION

According to the present invention there are provided triazine compounds selected from:

(i) a triaminotriazine compound of the formula C₃ N₆ (CH₂ OR)_(6-x) (CH₂ NHCOOR¹)_(x) ;

(ii) a benzoguanamine compound of the formula C₃ N₅ (C₆ H₅)(CH₂ OR)_(4-y) (CH₂ NHCOOR¹)_(y) ;

(iii) an oligomer of (i) or of (ii) ; or

(iv) a mixture of at least two of any of (i), (ii) and (iii), wherein the R groups are, independently, hydrogen or alkyl of from 1 to 12 carbon atoms, the R¹ groups are, independently, alkyl of from 1 to 20 carbon atoms, x is in the range of from about 2 to about 6, and y is in the range of from about 2 to about 4.

In preferred embodiments of the invention, x is in the range of from about 2.8 to about 6 and y is in the range of from about 2.2 to about 4. With respect to compound (i) R is lower alkyl, preferably C₁ -C₈ and R¹ is methyl, ethyl, n-propyl, i-propyl, butyl, n-octyl, 2-ethylhexyl, n-octadecyl, or a mixture of any of the foregoing. Also preferred are oligomers of (iii)(i) in which R is methyl and R¹ is methyl, ethyl, n-propyl, i-propyl, butyl or a mixture of any of the foregoing as well as benzoguanamines (ii) wherein R and R¹ are the same as defined above with respect to compound (i).

Also contemplated by the present invention are curable compositions comprising

(a) an active hydrogen-containing material;

(b) a triazine compound selected from

(i) a triaminotriazine compound of the formula C₃ N₆ (CH₂ OR)_(6-x) (CH₂ NHCOOR¹) _(x) ;

(ii) a benzoguanamine compound of the formula C₃ N₅)(C₆ H₅)(CH₂ OR)_(4-y) (CH₂ NHCOOR¹)_(y) ;

(iii) an oligomer of (i) or of (ii) ; or

(iv) a mixture of at least two of any of (i), (ii) and (iii), wherein the R groups are, independently, hydrogen or alkyl of from 1 to 12 carbon atoms, the R¹ groups are, independently, alkyl of from 1 to 20 carbon atoms, x is in the range of from about 2 to about 6, and y is in the range of from about 2 to about 4; and

(c) a cure catalyst.

In preferred features of this aspect of the invention, the active-hydrogen containing material (a) is a polymeric materral containing at least two reactive carboxyl, alcoholic hydroxy, amide or amine groups, or a mixture of such groups, or a group convertible to such groups, preferably a hydroxy-functional acrylic resin or a low molecular weight polyester polyol. Preferably the triazine will be as set forth specifically above, and the cure catalyst will be a metal salt or metal complex comprising tin, especially preferably tetrabutyldiacetoxy stannoxane.

Alternatively, the alkylcarbamylmethyl triazines can be used as a self-crosslinkable material in providing protective and/or decorative coatings.

Also provided by the invention are articles of manufacture comprising substrates protectively coated with a cured composition as defined above and articles of manufacture comprising a cured composition as defined above and a filler, e.g., glass, e.g., glass powder, glass beads, glass fibers or foundry sand.

DETAILED DESCRIPTION OF THE INVENTION

As starting materials to produce the alkylcarbamylmethylated triazines of this invention, there can be used the hydroxymethyl or alkoxymethyl melamines and/or benzoguanamines and oligmers thereof known in the art. Many of the starting materials are commercially available, and can be made by well known procedures. In accordance with the present invention, the starting materials are reacted with alkyl carbamates, such as methyl carbamate and propyl carbamate, which also are well known in this art, in the presence of an acid catalyst.

An idealized reaction equation for the preparation of the new compounds from an alkoxymethylmelamine or a hydroxymethylmelamine is as follows: ##STR3## wherein R, R¹ and x are as defined above.

The mole ratio of alkyl carbamate is selected to provide the desired degree of substitution. By way of illustration, from 2 to 6 moles can be used. Reaction is typically carried out by heating in the melt or in solution, e.g., in benzene, toluene, xylene, chlorobenzene, dichlorobenzene, e.g., in the presence of catalytic amounts of acid, e.g., para-toluenesulfonic acid, nitric acid, sulfuric acid, and the like, at temperatures between 80° and 150° C., preferably 90°-120° C. Measurement of the quantity of alcohol (ROH) evolved gives an indication of reaction completion. With 6 moles of alkyl carbamate, reaction is usually not 100% complete, unless forced, but a high degree of substitution, x=5-6, is obtained. Analysis by gel permeation chromotography shows that treatment of hexamethoxymethylolmelamine with substantially less than 6 moles of alkyl carbamate gives a product distribution similar to the starting material with degrees of substitution ranging up to 6. Of course, only those compounds wherein at least two carbamylmethyl groups are present are crosslinkers according to this invention, even though residual alkoxymethyl groups can provide crosslinking.

Instead of alkoxymethylmelamines, hydroxymethylmelamines, and the corresponding benzoguanamine analogs and oligomers can be used as starting materials. The products can be recovered by any convenient means after removal of byproduct water or alcohol is complete. Simply cooling to room temperature will leave the product as a residue, and the acid catalyst can be removed by neutralization.

The substituents defined by R and R¹ in the formulae above can vary widely in carbon content, and the groups can be straight chain, branched chain and alicyclic. A number of representative compounds will be exemplified in detail hereinafter.

The active hydrogen-containing materials have as the active hydrogen group a group selected from carboxyl, alcoholic hydroxyl, amido, primary amine, secondary amine (including imine), thiol and the like. The active hydrogen-containing materials useful herein are typically film-forming compositions. Illustrative examples of active hydrogen-containing materials are shown in the above-mentioned Koral patent, the above-mentioned German OLS 2,055,693, and in Valko, U.S. Pat. No. 4,435,559. Typical polymers are acrylic polymers, polyesters, epoxy resins, and the like, providing that they contain active hydrogen groups.

Especially suitable are polyesters and polyacrylates containing pendant hydroxyl groups as reaction sites. The former are obtained in a known manner by the reaction of polycarboxylic acids with excess quantities of polyhydric alcohols; the latter are obtained by the copolymerization of acrylic or methacrylic acid derivatives with hydroxyl-group-containing derivatives of these acids, such as, for example, the hydroxyalkyl esters, optionally with the simultaneous use of additional vinyl compounds, such as, for example, styrene. Hydroxyl-group-containing polyurethanes can be obtained in known manner by the reaction of polyisocyanates with excess quantities of compounds containing at least two hydroxy groups. Suitable commercially available hydroxy-group-containing polyesters are CYPLEX® 1473 and CYPLEX® 1531 from American Cyanamid Company and Cargil Polyester 5776. Suitable hydroxy- functional acrylic resins are available commercially from S.C. Johnson & Son, Inc. under the trademark JONCRYL®-500. Also suitable for use are a hydroxy-terminated polycaprolactone, as well as the copolymer of 50% styrene, 20% hydroxypropyl methacrylate and 30% butyl acrylate of Example 5 of the above-mentioned German OLS 2,055,693 and the polyester of phthalic acid, adipic acid, ethanediol, and trimethylolpropane, with a hydroxy number of 130 and an acid number of 1.5 of Example 6 of the said OLS publication.

As set forth herein, the curable composition includes a cure catalyst. Typically, the cure catalyst is a metal salt and/or complex of a metal such as lead, zinc, iron, tin and manganese, preferably tin. Suitable salts of these metals are, for example acetates, octoates, laurates and naphthanates. Suitable complexes, for example, are tetrabutyldiacetoxy stannoxane, dibutyltin dilaurate, dimethyltin dilaurate or an acetyl acetonate. The cure catalyst is used in amounts effective to accelerate cure at the temperatures employed, e.g., 120°-220° C. For example, the catalyst is used in amounts from about 0.1 to about 2.0 preferably 0.2 to 1% metal by weight (solids) based on the weight of the curable compositions.

It should also be understood that residual ether functional groups can cure with catalysts usually used with amino resins, such as acid catalysts, e.g., nitric acid, sulfuric acid, p-toluenesulfonic acid and the like. This may be advantageous where lower cure temperatures are useful, e.g., when binding fillers or reinforcements, e.g., textiles, cellulose, wood flour, etc. Also useful as heterogenous acidic catalysts are ion exchange resins in the acid form.

In the practice of the invention, the curable compositions can be adapted for use in solvent-based or water based coating compositions. Coating compositions comprising aqueous dispersions are particularly suited to application by electrodeposition. Generally the compositions will contain about 1 to 75 percent by weight of resin and crosslinker combined, and the weight ratio of crosslinker to resin will range from about 5 to about 40 parts to correspondingly from 60 to 95 parts of said resin.

In many instances a pigment composition and various conventional additives such as antioxidants, surface active agents, coupling agents, flow control additives, and the like, can be included. The pigment composition may be of any conventional type, such as, one or more pigments such as iron oxides, lead oxides, strontium chromate, carbon black, titanium dioxide, talc, barium sulfate, cadmium yellow, cadmium red, chromic yellow, or the like.

After deposition on a substrate, such as a steel panel, the coating composition is devolatilized and cured at elevated temperatures by any convenient method such as in baking ovens or with banks of infrared heat lamps. Curing can be obtained at temperatures in the range of from 120° C. to about 300° C., preferably from 150° C. to about 200° C. for from about 30 minutes at the lower temperatures to about 1 minute at the higher temperatures.

Conventional methods can be used to combine the novel aminotriazines herein with fillers and/or reinforcements and to shape them into useful articles by means well known to accomplish these functions with curable aminotriazine resins. Mixing with glass fillers for example and heating provides insulation shapes for pipes, and the like, after curing, and mixing with foundry sand and curing provides core molds for metal casting. These have superior strength compared to the state of the art and appear to be highly advantageous in not evolving formaldehyde during use.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

The following examples illustrate the compounds and compositions of the present invention. They are not to be construed as limiting the claims in any manner. All parts are by weight.

EXAMPLE 1 Reaction Product of 6 Moles of N-Propyl Carbamate With 1 Mole of Hexamethoxymethylmelamine (6-PC)

Hexamethoxymethylmelamine (47.2g, 0.121 mole, American Cyanamid Co. CYMEL® 300), n-propylcarbamate (75.0 g, 0.728 mole), and para-toluenesulfonic acid (0.33 g) are stirred at 95° C. in a flask equipped with a vacuum distillation head. During 50 minutes, the pressure is lowered in stages to 50 mm Hg and 21.1 g of methanol (0.659 mole, 91% of theoretical is collected in the distillate receiver. The product in the reaction flask is cooled to near room temperature, where it is a clear, colorless, very viscous liquid. Methylene chloride (100 ml) is added and stirring for one-half hour dissolves the product. The acid catalyst is removed by washing with sodium carbonate solution, followed by drying over potassium carbonate. Rotary vacuum evaporation gives 98.6 g of clear, colorless, nearly solid product. Nuclear magnetic resonance (NMR) analysis shows that the product has at least five (on average) of the methoxy groups replaced by n-propyl carbamate groups;

    C.sub.3 N.sub.6 (CH.sub.2 OCH.sub.3).sub.0-1 (CH.sub.2 NHCOOCH.sub.2 CH.sub.2 CH.sub.3).sub.5-6

Gel permeation chromatography shows one large peak for the monomeric compound (>80%) and two smaller peaks corresponding to dimeric (˜10%) and trimeric (˜3%) oligomers.

COMPARATIVE EXAMPLE 1A Reaction Product of 6 Moles of Phenyl Carbamate With 1 Mole of Hexamethoxymethylmelamine (6-PhC)

For comparison purposes, the procedure of Example 1 of German OLS 2005,693 is repeated: Hexamethoxymethyl-melamine (300 g, 1 mole) and 822 grams of phenylurethane (6 moles) are dissolved in two liters of chlorobenzene and, after the addition of 4 grams of p-toluenesulfonic acid, are heated with a vertical condenser, with stirring and passage of CO₂, until the boiling point of chlorobenzene is reached. The methanol cleavage starts at approximately 90° to 100° C. A mixture of methanol with a small amount of chlorobenzene comes over first. With increasing temperature, the boiling point of chlorobenzene (130° C.) is reached.

The mixture is then evaporated under vacuum, with stirring, to produce a colorless resin with a softening point of 85° to 120° C., which is soluble in all proportions in ethyl acetate. The yield is high. The product is of the formula CH₃ N₆ (CH₂ NHCOOC₆ H₅)₆.

EXAMPLE 2 Reaction Product of 6 Moles of Methyl Carbamate with One Mole of Hexamethoxymethylmelamine (6-MC)

Hexamethoxymethylmelamine (19.5 g, 0.05 mole), excess methyl carbamate (37.6 g, 0.50 mole), and paratoluene-sulfonic acid (0.86 g, 0.005 mole) are stirred at 97° C. in a flask equipped with a distillation head as in Example 1. The reaction mixture changes from a clear, colorless liquid to a white solid and a few ml. of distillate is formed. The reaction mixture is then allowed to cool to room temperature.

A portion, 20.0 g, of the solid product is powdered and vigorously stirred with 100 ml. of of water at room temperature for 11/2 hours. Filtration and drying gives 12.3 g of white solid; m.p.=179°-188° C. Infrared spectroscopy shows that at least 90-95% of the methoxy groups have been replaced by carbamate groups.

Purified product, 31.7 g, amounts to 98% of the theoretical yield of hexamethylcarbamylmethylated melamine, a compound of the formula

    C.sub.3 N.sub.6 (CH.sub.2 NHCOOCH.sub.3).sub.6

EXAMPLE 3 Reaction Product of 2 Moles of n-Octadecyl Carbamate With 1 Mole of Hexamethoxymethylmelamine

Hexamethoxymethylmelamine (25.0 g, 0.0641 mole), n-octadecyl carbamate (40.1 g, 0.128 mole), and 0.31 g (0.0018 mole) of para-toluenesulfonic acid are stirred at 100° C. in a flask equipped with a vacuum distillation head. During 30 minutes, the pressure is lowered in stages to 50 mm Hg and distillate is collected in the receiver.

At room temperature the product is opaque, white and has the consistency of mayonnaise. Gas chromatographic analysis of a sample of the product dissolved in methyl isobutyl ketone shows practically no unconverted octadecyl carbamate. The formula is, approximately:

    C.sub.3 N.sub.6 (CH.sub.2 OCH.sub.3).sub.4 (CH.sub.2 NCOOC.sub.18 H.sub.37 --n).sub.2

EXAMPLE 4 Reaction Product of 6 Moles of Isopropyl Carbmate With 1 Mole of Hexamethoxymethylmelamine

Hexamethoxymethylmelamine (18.9 g, 0.0485 mole), isopropyl carbamate (30.0 g, 0.291 mole), and para-toluene-sulfonic acid (0.13 g., 0.008 mole) and stirred at 95° C. in a flask equipped with a vacuum distillation head. During 45 minutes, the pressure is lowered in stages to 50 mm Hg, and 8.46 g of methanol (0.264 mole, 91% of theoretical) is collected in the distillate receiver. The product is dissolved in 75 ml of methylene chloride and the solution is washed with two portions of aqueous 5% sodium carbonate to remove the acid catalyst. The solution is dried over anhydrous potassium carbonate and rotary vacuum evaporated to give 36 8 g of colorless solid (93% yield). The solid is pulverized to white powder; m.p. 101° to 130° C. (clear, colorless melt). The formula is, approximately:

    C.sub.3 H.sub.6 (CH.sub.2 NHCOOCH(CH.sub.3).sub.2).sub.6

EXAMPLE 5 Reaction Product of 2 Moles of n-Octyl Carbamate With 1 Mole of Hexamethoxymethylmelamine

Hexamethoxymethylmelamine (22.6 g, 0.0579 mole), n-octyl carbamate (20.0 g, 0.116 mole), and para-toluene-sulfonic acid (0.19 g, 0.0011 mole) are stirred at 75° C. in a flask equipped with a vacuum distillation head. During 50 minutes, the pressure is lowered in stages to 50 mm Hg, and 3.58 g of methanol (0.112 mole, 96% of theoretical) is collected in the distillate receiver. The product is dissolved in 150 ml of methylene chloride and the solution is washed with two portions of aqueous 5% sodium carbonate to remove the acid catalyst. The solution is dried over anhydrous potassium carbonate and rotary vacuum evaporated to give 37.2 g of almost-clear, colorless, viscous liquid (96% yield of theoretical product). The infrared spectrum is consistent with the expected structure. Gel permeation chromatography shows peaks attributed to mono-, di-, tri-, and higher-substituted products; little oligomeric material is evident. The formula is, approximately:

    C.sub.3 N.sub.6 (CH.sub.2 OCH.sub.3).sub.4 (CH.sub.2 NHCOOC .sub.8 H.sub.17 --n).sub.2

EXAMPLE 6 Reaction Product of 6 Moles of n-Propyl Carbamate With 1 Mole of Hexamethylolmelamine

The general procedure of Example 1 is repeated, substituting the hydroxymethyltriazine Hexamethylolmelamine (10.0 g, 0.0327 mole), n-propyl carbamate (20.2 g, 0.196 mole), and para-toluenesulfonic acid (0.60 g, 0.0035 mole) are stirred at 95° C. in a flask equipped with a vacuum distillation head. During 30 minutes, the pressure is lowered in stages to 50 mm Hg., and 3.24 g. of distillate (mostly water, 92% of theoretical) is collected in the distillate receiver. At room temperature, the product in the reaction vessel is a gray-white solid. The infrared spectrum shows little or no residual hydroxyl functionality and is similar to the spectrum of authentic hexa-n-propylcarbamylmethylated melamine, made by Example 1. The general formula is, approximately:

    C.sub.3 N.sub.6 (CH.sub.2 NHCOOC.sub.3 H.sub.7 --n).sub.6

EXAMPLE 7 Reaction Product of 3.5 Moles of n-Propyl Carbamate with 1 Mole of Hexamethoxymethylmelamine

The general procedure of the preceding Examples is used to react hexamethoxymethylmelamine (167.8 g, 0.430 moles) with 155.1 g, 1.566 moles of n-propyl carbamate. The acid catalyst in this instance is 0.7 g of concentrated nitric acid. The product weighs 254.2 g and contains only 0.1% residual carbamate. It melts at 85°-95° C. A 65% solids solution in xylene remains clear and colorless for 8 weeks. It has the formula, approximately:

    C.sub.3 N.sub.6 (CH.sub.2 OCH.sub.3).sub.2.5 (CH.sub.2 NHCOOC.sub.3 H.sub.7 -n).sub.3.5

EXAMPLE 8 Reaction Product of 3.5 Moles of Methyl Carbamate With 1 Mole of Hexamethoxymethylmelamine

The procedure of Example 7 is repeated substituting 1.589 moles of methyl carbamate. The product weighs 241.7 g and melts at 95°-103° C. It has the formula, approximately:

    C.sub.3 N.sub.6 (CH.sub.2 OCH.sub.3).sub.2.5 (CH.sub.2 NHCOOCH.sub.3).sub.3.5

EXAMPLE 9 Reaction Product of 3.5 Moles of n-Propyl Carbamate With 1 Mole of Hexamethoxymethylmelamine Oligomer

The procedure of Example 7 is repeated, substituting an oligomeric triazine (American Cyanamid Co. CYMEL® 303), C₃ N₆ (CH₂ OCH₃)₅.25. The catalyst is removed by extracting a xylene solution of the product mixture with sodium carbonate solution. A 75% solution in xylenes remains clear and colorless for more than 6 weeks. The product melts at 74°-80° C. The formula is, approximately:

    C.sub.3 N.sub.6 (CH.sub.2 OCH.sub.3).sub.1.75 (CH.sub.2 NHCO.sub.2 C.sub.3 H.sub.7).sub.3.5

EXAMPLE 10 Reaction Product of 4 Moles of n-Propyl Carbamate With 1 Mole of Hexamethoxymethylmelamine Oligomer

The procedure of Example 9 is repeated with the higher mole ratio of n- propyl carbamate. The product, 412.2 g, melts at 80°-90° C. At 75% solids in xylenes and methyl isobutyl ketone, the product in solution remains clear and colorless for more than 6 weeks. It has the following approximate formula:

    C.sub.3 N.sub.6 (CH.sub.2 OCH.sub.3).sub.1.25 (CH.sub.2 NHCOOC.sub.3 H.sub.7 --n).sub.4.0

EXAMPLE 11 Reaction Product of 5 Moles of n-Propyl Carbamate With 1 Mole of Hexamethoxymethylmelamine Oligomer

The procedure of Example 9 is repeated with a higher mole ratio of n-propyl carbamate. The product, 32.4 g, melts at 80°-92° C. It has the following approximate formula:

    C.sub.3 N.sub.6 (CH.sub.2 OCH.sub.3).sub.0.25 (CH.sub.2 NHCOOC.sub.3 H.sub.7 --n).sub.5.0

EXAMPLE 12 Reaction Product of 4 Moles of n-Propyl Carbamate and 2 Moles of Methyl Carbamate With 1 Mole of Hexamethoxymethylmelamine

The general procedure of Example 9 is used at 95° C. The product, 95.8 g, melts at 85°-95° C. The formula is, approximately:

    C.sub.3 N.sub.6 (CH.sub.2 NH--CO.sub.2 CH.sub.3).sub.1.25 (CH.sub.2 NHCO.sub.2 C.sub.3 H.sub.7 --n).sub.4

EXAMPLE 13 Reaction Product of 5.25 Moles of n-Propyl Carbamate With 1 Mole of Hexamethoxymethylmelamine Oligomer

The general procedure of Example 9 is used. The product weighs 113.5 g and melts at 90°-100° C. The formula is, approximately:

    C.sub.3 N.sub.6 (CH.sub.2 OCH.sub.3).sub.0.15 (CH.sub.2 NHCOOC.sub.3 H.sub.7 --n).sub.5.1

EXAMPLE 14 Reaction Product of 2.5 Mole of n-Propyl Carbamate and 2.5 Mole of Methyl Carbamate With 1.0 Mole of Hexamethoxymethylmelamine Oligomer

The general procedure of Example 9 is used at 110° C. The product weighs 174.5 g and melts at 85°-95° C. The general formula is, approximately:

    C.sub.3 N.sub.6 (CH.sub.2 OCH.sub.3).sub.0.25 (CH.sub.2 NHCO.sub.2 CH.sub.3).sub.2.5 (CH.sub.2 NHCO.sub.2 C.sub.3 H.sub.7 --n).sub.2.5

EXAMPLE 15 Reaction Product of 3.5 Mole of n-Propyl Carbamate with 1 Mole of (Trimethoxymethyl -Tributoxymethyl) Melamine

(Trimethoxymethyl-tributoxymethyl)melamine (CYMEL® 1133, American Cyanamid Co., 320.3 g, 0.689 mole), n-propyl carbamate (248.3 g, 2.411 mole) and 1.12 g of concentrated nitric acid are stirred and heated in a 100° C. oil bath under a steady stream of nitrogen. Distillate is collected in a dry-ice/isopropanol cooled trap. After 60 minutes, during which vacuum of up to 50 mm Hg is applied, the reaction is stopped. The hot, crude reaction product is dissolved to 30% solids in mixed xylenes (1059 g of xylenes are added) and extracted once with 300 ml of 5% aqueous sodium carbonate solution. The organic layer is then extracted several times with hot deionized water to neutralize the acid and reduce the amount.of residual n-propyl carbamate. The organic layer is dried over potassium carbonate (anhydrous) until clear and then stripped under vacuum of a 65% solids content. The product weighs 698.5 grams.

EXAMPLE 16 Reaction Product of 3.5 Mole of Methyl Carbamate with 1 Mole of (Trimethoxymethyl -Tributoxymethyl)Melamine

The procedure of Example 15 is repeated, substituting 376.28 g, 0.809 mole of trimethoxymethyl tributoxymethylmelamine, 212.42 g, 2.832 mole of methyl carbamate and 1.32 g of conc. nitric acid. The product is recovered by the procedure of Example 9.

In the following examples, the alkylcarbamylmethylated triazines of this invention are formulated into curable compositions and evaluated as coatings. For comparison purposes, the phenylcarbamylmethylated triazine of German OLS 2,005,693 (Example 1A herein) is also evaluated.

The general method of preparation is as follows:

Thermosetting coatings containing polyols with alkyl and phenylcarbamylmethylated melamines on steel are prepared by mixing high solids solutions of alkylcarbamyl and arylcarbamylmethyl melamines (65% solids in methyl isobutyl ketone or xylene) with a solution of a hydroxyl functional acrylic resin (specifically, JONCRYL®-500, S.C. Johnson & Son, Inc.; 85% solids in methyl amyl ketone), a solution of a tin catalyst (tetrabutyldiacetoxy stannoxane, TBDSA, 10% solids in methyl isobutyl ketone), and a flow control additive (FC-431, 10% solids in ethyl acetate, 3M Co.). A second series of coatings compositions is prepared as above but with low molecular polyester polyol as backbone resin (specifically, CYPLEX® 1473, 60% solids in Xylene, American Cyanamid Co.). Both systems are formulated with and without EPON®-1001, an epoxy resin (10 parts per hundred-phr, as an 85% solids solution in methyl isobutyl ketone--Shell Co.) to assess resistance properties in particular.

The coatings are applied using #40 or #46 WIRE CATORS® by drawdown of resin formulations on 4"×12" BONDERITE®-100 treated steel panels. The panels, after drawdown, are held for 10 minutes at room temperature and then cured on racks in a temperature controlled oven, at specified temperatures. The coatings prepared are about 1.2±0.2 mils thick and initially tested for solvent resistance by rubbing with a cloth saturated with methyl ethyl ketone (MEK rubs) in accordance with standard testing methods.

Table 1 illustrates a typical charge composition for preparing a coated panel.

                  TABLE 1                                                          ______________________________________                                         Material    % Solids PHR*    Charge (Grams solution)                           ______________________________________                                         CYPLEX ® 1475-5                                                                        65       70      32.3                                              Propyl Carbamate                                                                           60       20      10.0                                              Melamine resin                                                                 1001 ®  75       10      4.0                                               TBDAS cat.  10       1       3.0                                               FC-431      10       0.13    0.4                                               ______________________________________                                          *PHR = parts per hundred resin; final solution 57.8% solids.             

Materials 1-5 are stirred until homogeneous, then filtered through a 10 micron felt filter to remove small particles and deaerated.

    ______________________________________                                         Property         Method                                                        ______________________________________                                         Forward and Reverse Impact                                                                      ASTM D-3281-73                                                Color            Visual                                                        20° Gloss Measured on Glossgard II                                                       20°/60° Gossmeter - Neotec                                       Instr. Div., Pacific                                                           Scientific                                                    Detergent Resistance at 72° C.                                                           ASTM D-2248-73; reapproved                                                     1982; Evaluation of Degree                                                     of Blistering of Paints D-714                                 Blister Classification                                                                          Example: F-8 means few small                                                   blisters; D-4 means dense                                                      large blisters. The smaller                                                    the number following the                                                       letter, the larger the                                                         blister on a scale of 1-10,                                                    with 10 meaning no blistering.                                ______________________________________                                    

EXAMPLES 17-22

The crosslinker of Example 1 herein, the reaction product of 6 moles of n-propyl carbamate and 1 mole of hexamethoxymethyl melamine (6-PC), is used with a hydroxy functional polyacrylate and tetrabutyldiacetoxystannoxane as cure catalyst. For comparison purposes, formulations are made substituting the reaction product of 6 moles of phenyl carbamate with hexamethoxymethyl melamine (6-PhC) of Comparative Example 1A. The formulations used and the properties of the cured films are set forth in Table 2.

                  TABLE 2                                                          ______________________________________                                         Carbamylmethylated Melamine                                                    Crosslinked Acrylic Resin                                                      ______________________________________                                                Example                                                                          17      18      19    20    21    22                                  ______________________________________                                         Composition                                                                    (parts by                                                                      weight)                                                                        Polyacrylate.sup.a                                                                      80      70      60    50    80    60                                  6-PC.sup.b                                                                              20      20      40    40    20    40                                  6-PhC.sup.c                                                                             --      --      --    --    --    --                                  Epoxy Resin.sup.d                                                                       --      10      --    10    --    --                                  TBDAS.sup.e                                                                             1       1       1     1     1     1                                   Cure Temp.,                                                                             180     180     180   180   160   160                                 °C.                                                                     Cure Time,                                                                              20      20      20    20    30    30                                  min.                                                                           Properties                                                                     MEK wipes                                                                               200+    200+    200+  200+  200+  200+                                Thickness,                                                                              1.2     1.1     1.0   1.0   1.2   1.1                                 mils.                                                                          Forward  30      10      10    20    20    --                                  Impact,                                                                        Color    Clr     Clr     Clr   Clr   Clr   Clr                                 20° Gloss                                                                        97      93      95     93   97    96                                  Knoop Hard-                                                                               13.5  13      16      15.8                                                                                 10.8                                                                                 16.2                              ness                                                                           Detergent                                                                      Immersion                                                                       72 hrs  M8      10      F9    10    M8    D9                                   120 hrs D8      10      F8    10    M6    D8                                   192 hrs D8      D9      F9    10    D7    M9                                   240 hrs --      --      --    10    --    --                                   288 hrs --      --      --    10    --    --                                   408 hrs --      --      --    10    --    --                                   456 hrs --      --      --    10    --    --                                   744 hrs --      --      --    10    --    --                                   912 hrs --      --      --    10    --    --                                  1100 hrs --      --      --    10    --    --                                  ______________________________________                                                Example                                                                          17      18      19    20    21    22                                  ______________________________________                                         Composition                                                                    (parts by                                                                      weight)                                                                        Polyacrylate.sup.a                                                                      80      70      60    50    80    60                                  6-PC.sup.b                                                                              --      --      --    --    --    --                                  6-PhC.sup.c                                                                             20      20      40    40    20    40                                  Epoxy Resin.sup.d                                                                       --      10      --    10    --    --                                  TBDAS.sup.e                                                                             1       1       1     1     1     1                                   Cure Temp.,                                                                             180     180     180   180   160   160                                 °C.                                                                     Cure Time,                                                                              20      20      20    20    30    30                                  min.                                                                           Properties                                                                     MEK wipes                                                                               --      200.sup.m                                                                              200+  200+  200.sup.m                                                                            --                                  Thickness,                                                                              1.1     0.94    0.88  0.83  1.2   1.0                                 mils.                                                                          Forward  --      20      20    20    10    --                                  Impact,                                                                        Color    Clr     Yel     Sl. Brn                                                                              Yel   Sl.Yel                                                                               Clr                                 20° Gloss                                                                        94      97      95    91    92    86                                  Knoop    15.3    13      18    17    12.4  19.4                                Hardness                                                                       Detergent                                                                      Immersion                                                                       72 hrs  M6      10      F6    10    VD6   M8                                   120 hrs D2      M8      F8    10    VD4   M8                                   192 hrs --      D8      F8    10    --    M8                                   240 hrs --      --      --    10    --    --                                   288 hrs --      --      --    10    --    --                                   408 hrs --      --      --    10    --    --                                   456 hrs --      --      --    F6    --    --                                   744 hrs --      --      --    F6    --    --                                   912 hrs --      --      --    F6    --    --                                  1100 hrs --      --      --    F6    --    --                                  ______________________________________                                          .sup.a JONCRYL ® S. C. Johnson & Son, Inc., 85% solids in                  methylamylketone;                                                              .sup.b npropylcarbamylmethyl melamine (Example 1);                             .sup.c phenylcarbamylmethyl melamine (Comp. Ex. 1A);                           .sup.d EPON ® 1001, Shell Polymers Inc.;                                   .sup.e Tetrabutyldiacetoxy stannoxane;                                         .sup.m = marred; and s = softened                                        

EXAMPLES 23-30

The crosslinkers of Examples 7 and 8 herein (3.5 PC and 3.5 MC) are used to crosslink the hydroxy functional acrylic resin and evaluated in coatings. The formulations used and the properties obtained are set forth in Table 3:

                                      TABLE 3                                      __________________________________________________________________________     Carbamylmethylated Melamine-Crosslinked Acrylic Resins                                    Example                                                                        23  24  25  26  27  28  29  30                                      __________________________________________________________________________     Composition                                                                    (parts by weight)                                                              Polyacrylate.sup.a                                                                        80  70  60  50  80  70  60  50                                      3.5-PC.sup.b                                                                              20  20  40  40  --  --  --  --                                      3.5-MC.sup.c                                                                              --  --  --  --  20  20  40  40                                      Epoxy Resin.sup.d                                                                         --  10  --  10  --  10  --  10                                      TBDAS.sup.e                                                                               1   1   1   1   1   1   1   1                                       Cure Temp., °C.                                                                    180 180 180 180 160 160 180 180                                     Cure Time, min.                                                                           20  20  20  20  20  20  20  20                                      Properties                                                                     MEK wipes  200+                                                                               200+                                                                               200+                                                                               200+                                                                               200+                                                                               200.sup.m                                                                          200+                                                                               200                                     Thickness, mils.                                                                          1.0 1.1 1.2 1.1 1.0 1.0 0.95                                                                               0.96                                    Forward Impact,                                                                           30  5   20  18.5                                                                               30  15  15  20                                      Color      Clr Clr Clr Clr Clr Clr Clr Clr                                     20° Gloss                                                                          90  95  95  91  97.5                                                                               99.5                                                                               101 101                                     Knoop Hardness                                                                            11.8                                                                               10.4                                                                               15.4                                                                               18.5                                                                               13  15  16.4                                                                               17                                      Detergent Immersion                                                             48 hrs    M8  --  --  --  --  --  --  --                                       72 hrs    --  10  M8  10  M9  10  10  10                                       120 hrs   D8  D8  M4  10  D6  10  10  10                                       192 hrs   --  D8  D8  10  D8  10  10  10                                       240 hrs   --  --  --  10  --  M8  F8  10                                       288 hrs   --  --  --  10  --  --  F8  10                                       408 hrs   --  --  --  10  --  --  M6  10                                       456 hrs   --  --  --  10  --  --  M4  10                                       744 hrs   --  --  --  10  --  --  M4  10                                       912 hrs   --  --  --  10  --  --  M4  10                                      1100 hrs   --  --  --  10  --  --  --  10                                      1400 hrs   --  --  --  10  --  --  --  F9                                      __________________________________________________________________________      .sup.a See footnote Table 2                                                    .sup.b 3.5 propyl carbamylmethylmelamine (Ex. 7)                               .sup.c 3.5 methyl carbamyl methylmelamine (Ex. 8)                              .sup.d See footnote Table 2                                                    .sup.e See footnote Table 2                                              

EXAMPLES 31-34

The crosslinker of Example 1 herein, the reaction product of 6 moles of n-propyl carbamate and 1 mole of hexamethoxymethylolmelamine (6-PC) is used with a low molecular weight hydroxyfunctional polyester and tetrabutyldiacetoxy stannoxane as cure catalyst. For comparison purposes, formulations are made substituting the reaction product of 6 moles of phenylcarbamate with hexamethoxymethylmelamine (6-PhC) of Comparative Example 1A. The formulations used and the properties of the cured films are set forth in Table 4:

                  TABLE 4                                                          ______________________________________                                         Carbamylmethylated Melamine-                                                   Crosslinked Polyester Resin                                                    ______________________________________                                                    Example                                                                          31      32      33    34    31A                                   ______________________________________                                         Composition                                                                    (parts by weight)                                                              Polyester.sup.a                                                                             80      70      60    50    80                                    6-PC.sup.b   20      20      40    40    --                                    6-PhC.sup.c  --      --      --    --    20                                    Epoxy Resin.sup.d                                                                           --      10      --    10    --                                    TBDAS.sup.e  1       1       1     1     1                                     Cure Temp., °C.                                                                      180     180     180   180   180                                   Cure Time, min.                                                                             20      20      20    20    20                                    Properties                                                                     MEK wipes    200.sup.s                                                                              200+    200   200+  200.sup.s                             Thickness, mils.                                                                            .98     1.0     .90   1.0   .92                                   Reverse impact,                                                                             160     --      40    --    160                                   Forward Impact,                                                                             160     --      70    --    160                                   Color        Clr     Clr     Clr   Clr   Clr/                                                                           Yel                                   20° Gloss                                                                            99      102     104   102   92                                    Knoop Hardness                                                                              15.4    18.8    19.5  18.8  14.6                                  Detergent Immersion                                                             48 hrs      --      10      --    10    --                                     72 hrs      10      --      10    --    10                                     96 hrs      10      --      10    --    M8                                     168 hrs     --      10      10    10    --                                     216 hrs     M6      10      F8    10    D4                                     336 hrs     --      M8      --    10    --                                     398 hrs     M2      --      M4    --    --                                     504 hrs     --      D4-6    M2    10    --                                     652 hrs     --      --      --    F8    --                                    ______________________________________                                                    Example                                                                          32A     33A     34A   34B   34C                                   ______________________________________                                         Composition                                                                    (parts by weight)                                                              Polyester.sup.a                                                                             70      60      50    80    60                                    6-PC.sup.b   --      --      --    --    --                                    6-PhC.sup.c  20      40      40    40    40                                    Epoxy Resin.sup.d                                                                           10      --      10    --    --                                    TBDAS.sup.e  1       1       1     1     1                                     Cure Temp., °C.                                                                      180     180     180   160   160                                   Cure Time, min.                                                                             20      20      20    30    30                                    Properties                                                                     MEK wipes    --      200     200   200   200.sup.m                             Thickness, mils.                                                                            1.1     .85     .85   .95   .65                                   Reverse impact,                                                                             --      140     30    160   160                                   Forward Impact,                                                                             --      150     70    160   160                                   Color        Clr     Yel     SlYel Clr   Clr                                   20° Gloss                                                                            106     107     105   98    101                                   Knoop Hardness                                                                              19.1    21      22.5  16.2  21                                    Detergent Immersion                                                             48 hrs      --      --      --    --    --                                     72 hrs      10      M8      10    10    F8                                     96 hrs      --      D8      10    10    M6                                     168 hrs     --      --      10    --    --                                     216 hrs     10      D4      F8    F9    D8                                     336 hrs     --      --      --    --    --                                     398 hrs     10      --      D4    D2    D2                                     504 hrs     --      --      --    --    --                                     652 hrs     D8      --      --    --    --                                    ______________________________________                                          .sup.a American Cyanamid Co., CYPLEX ® 14735                               .sup.b-f See footnote above, Table 2.                                    

EXAMPLES 35-44

The crosslinkers of Examples 7 and 8, (3.5-PC and 3.5-MC) are used with the low molecular weight hydroxyfunctional polyester and tetrabutyldiacetoxystannoxane as cure catalyst. The formulations used and the results obtained are set forth in Table 5:

                  TABLE 5                                                          ______________________________________                                         Carbamylmethylated                                                             Melamine-Crosslinked                                                           Polyester Resins                                                               ______________________________________                                                    Example                                                                          35      36      37    38    39                                    ______________________________________                                         Composition                                                                    (parts by weight)                                                              Polyester.sup.a                                                                             80      70      60    50    80                                    3.5-PC.sup.b 20      20      40    40    --                                    3.5-MCc      --      --      --    --    20                                    Epoxy Resin.sup.d                                                                           --      10      --    10    --                                    TBDAS.sup.e  1       1       1     1     1                                     Cure Temp., °C.                                                                      180     180     180   180   180                                   Cure Time, min.                                                                             20      20      20    20    20                                    Properties                                                                     MEK wipes    200.sup.m                                                                              200+    200.sup.s                                                                            200+  200+                                  Thickness, mils.                                                                            .92     .9      .77   .96   .88                                   Reverse impact,                                                                             160     --      120   --    150                                   Forward Impact,                                                                             160     100     120   70    160                                   Color        Clr     Clr     Clr   Sl.Yl.                                                                               Clr                                   20° Gloss                                                                            96      85      95    90    99                                    Knoop Hardness                                                                              14.2    17.4    18.8  21    14.4                                   Detergent Immersion                                                            48 hrs      10      10      --    --    --                                     72 hrs      --      --      10    10    10                                     96 hrs      --      --      10    10    M8                                    168 hrs      M6      10      --    --    --                                    216 hrs      D2      M8      M6    10    D4                                    336 hrs      --      D2      --    --    --                                    398 hrs      --      --      D2    F8    --                                    504 hrs      --      --      --    F6    --                                    ______________________________________                                                    Example                                                                          40      41      42    43    44                                    ______________________________________                                         Composition                                                                    (parts by weight)                                                              Polyester.sup.a                                                                             70      60      50    80    60                                    3.5-PC.sup.b --      --      --    --    --                                    3.5-MC.sup.c 20      40      40    20    40                                    Epoxy Resin.sup.d                                                                           10      --      10    --    --                                    TBDAS.sup.e  1       1       1     1     1                                     Cure Temp., °C.                                                                      180     180     180   160   160                                   Cure Time, min.                                                                             20      20      20    30    30                                    Properties                                                                     MEK wipes    200+    200+    200+  --    --                                    Thickness, mils.                                                                            1.2     .85     1.1   1.1   1.0                                   Reverse impact,                                                                             50      80      10    --    --                                    Forward Impact,                                                                             50      80      40    --    --                                    Color        Sl.Yl.  Clr     Sl.Yl.                                                                               Clr   Clr                                   20° Gloss                                                                            101     99      102   101   102                                   Knoop Hardness                                                                              20      22.5    23.5  18    17.2                                  Detergent Immersion                                                             48 hrs      --      --      --    --    --                                     72 hrs      10      10      10    10    10                                     96 hrs      10      M8      10    10    10                                    168 hrs      --      --      --    --    --                                    216 hrs      10      D4      10    F8    10                                    336 hrs      --      --      --    --    10                                    398 hrs      10      --      10    M4    haze                                  504 hrs      --      --      10    --    VD8                                   652 hrs      --      --      VF8   VD2   --                                    ______________________________________                                          .sup.a See footnote above, Table 4                                             .sup.b See footnote above, Table 3                                             .sup.c See footnote above, Table 3                                             .sup.d See footnote above, Table 3                                             .sup.e See footnote above, Table 3                                             .sup.m See footnote above, Table 3                                             .sup.s See footnote above, Table 3                                       

A review of the data in the foregoing tables indicates that improved properties are obtained with the alkylcarbamylmethylated melamines of this invention in comparison with the phenylcarbamylmethylated melamine of the prior art. Particularly outstanding with the acrylic and polyester coatings are the excellent detergent resistance properties of the new alkylcarbamylmethylated melamines. For example, both the methyl and propyl carbamylmethylated melamines give over 1100 hours of blister free coatings in a detergent bath when formulated with acrylic polyol and Epon-1001 versus 408 hours for the phenyl system. In the polyester system, the alkylcarbamate system gives 504 hours of blister free coatings versus 398 hours for the phenylcarbamate system in a detergent bath.

EXAMPLES 45-52

Unpigmented coating formulations are prepared by the general procedure described above and cured on steel panels at 177° C. for 6-PC and benzoguanamine resins (CYMEL® 1123) and at 125° C. for melamine oligomer methoxy methyl (CYMEL® 303) resins, using hydroxy functional polyesters and 20 min. cure times. In addition to detergent resistance, salt spray resistance and pencil hardness are measured. The formulations used and the results obtained are set forth in Table 6, as follows:

                  TABLE 6                                                          ______________________________________                                         Carbamylmethylmelamine-Cured Polyesters                                        ______________________________________                                                    Example                                                                          45      46      47    48    49                                    ______________________________________                                         Composition                                                                    (parts by weight)                                                              Polyester    60      70      75    80    85                                    (CYPLEX ® 1473-5)                                                          6-PC         40      30      25    20    15                                    CYMEL ® 303                                                                             --      --      --    --    --                                    CYMEL ® 1123                                                                            --      --      --    --    --                                    EPON ® 1001                                                                             --      --      --    --    --                                    TBDAS        1       1       1     1     1                                     p-TSA        --      --      --    --    --                                    Properties                                                                     Pencil hardness                                                                             3H-4H   2H-3H   2H-3H 3H    2H-3H                                 Knoop hardness                                                                              23      16.4    16.6  17.5  16                                    Reverse Impact                                                                              60      150     150   160   160                                   T-Bond       T5      T2      T4    T3    T1                                    Detergent Resistance,                                                          Blister Code, Hrs.                                                              48          F9      F8      M9    M9    M8                                     72          M8      M8      M8    M8    M8                                    216          D7      D6      D7    D7    D6                                    384          D7      D4      D6    D6    D4                                    Salt Spray Exposure                                                            Blister Code, 46 Hrs.                                                                       10      10      10    10    F8                                    Tape Pull, mm                                                                               0       1       1     1     0                                     168  hrs         10      10    10    10    10                                       mm          1       2     2     2     3                                   300  hrs         10      10    10    10    10                                       mm          2.5     2     2.5   2     4                                   468  hrs         10      10    10    10    10                                       mm          4       3.5   4     3.5   5                                   ______________________________________                                                    Example                                                                          50      51      52    50A   51A                                   ______________________________________                                         Composition                                                                    (parts by weight)                                                              Polyester    75      70      65    75    75                                    (CYPLEX ® 1473-5)                                                          6-PC         15      20      25    --    --                                    CYMEL ® 303                                                                             --      --      --    15    --                                    CYMEL ® 1123                                                                            --      --      --    --    15                                    EPON ® 1001                                                                             10      10      10    10    10                                    TBDAS        1       1       1     --    --                                    p-TSA        --      --      --    .4    .4                                    Properties                                                                     Pencil hardness                                                                             2H-3H   3H-4H   4H-5H 2H-3H H-2H                                  Knoop hardness                                                                              16      21.5    19.4  15.6  15.5                                  Reverse Impact                                                                              160     160     160   160   150                                   T-Bond       T2      T4      T4    T2    T4                                    Detergent Resistance,                                                          Blister Code, Hrs.                                                              48          10      10      10    10    10                                     72          10      10      10    10    10                                    216          10      F9      10    (168- D7                                                                       D9)                                         384          10      D9      10    --    D4                                    Salt Spray Exposure                                                            Blister Code, 46 Hrs.                                                                       10      10      10    10    10                                    Tape Pull, mm                                                                               0       0       0     0     0                                     168  hrs         10      10    10    --    10                                       mm          0       0     0     --    0                                   300  hrs         10      10    10    --    10                                       mm          0       0     0     --    0                                   468  hrs         10      10    10    --    --                                       mm          0       0     0     --    --                                  1080 hrs         10      10    10    D4    F2                                       mm          0       0     0     0     4                                   1440 hrs         10      10    10    M4/6  --                                       mm          0       0     0     Striped                                                                              --                                  ______________________________________                                    

EXAMPLES 53-60

Unpigmented coating formulations are prepared by the general procedure described above and cured on steel panels at 177° C. for 6-PC and at 125° C. for the melamine oligomer resin, using a different hydroxyfunctional polyester and a 20 min. cure time. The formulations used and the results obtained are set forth in Table 7, as follows:

                  TABLE 7                                                          ______________________________________                                         Carbamylmethylmelamine-Cured Polyesters                                        ______________________________________                                                    Example                                                                          53      54      55    56    57                                    ______________________________________                                         Composition                                                                    (parts by weight)                                                              Polyester    60      67      70    75    80                                    (CYPLEX ® 1473-5)                                                          6-PC         40      33      30    25    20                                    CYMEL ® 303                                                                             --      --      --    --    --                                    EPON ® 1001                                                                             --      --      --    --    --                                    TBDAS        1       1       1     1     1                                     p-TSA        --      --      --    --    --                                    Properties                                                                     Pencil hardness                                                                             4H      4H      4H    2H-3H 2H-3H                                 Knoop hardness                                                                              16.6    16.4    16.4  15.2  14.2                                  Reverse Impact                                                                              40      110     120   160   160                                   T-Bond       T4      T3      T3    T3    T2                                    Detergent Resistance,                                                          Blister Code, Hrs.                                                              48          F9      F9      F9    M9    F9                                     72          F9      F8      F9    M8    F9                                    216          D6      D6      D7    D8    D8                                    384          M/D7    D5      D7    D7    D7                                    Salt Spray Exposure                                                            Blister Code, 46 Hrs.                                                                       10      10       10   10    10                                    Tape Pull, mm                                                                               0       1       0     2     1                                     168  hrs         10      10    10    10    10                                       mm          0       2     2     3     2                                   300  hrs         10      10    10    10    10                                       mm          0       2     4     4     4                                   468  hrs         10      10    10    10    10                                       mm          1       4     5     6     6                                   1080 hrs         --      --    --    --    --                                       mm          --      --    --    --    --                                  1440 hrs         --      --    --    --    --                                       mm          --      --    --    --    --                                  ______________________________________                                                    Example                                                                          58      59      60    58A   58B                                   ______________________________________                                         Composition                                                                    (parts by weight)                                                              Polyester    75      70      65    75    75                                    (CYPLEX ® 1473-5)                                                          6-PC         15      20      25    --    --                                    CYMEL ® 303                                                                             --      --      --    25    15                                    EPON ® 1001                                                                             10      10      10    --    10                                    TBDAS        1       1       1     --    --                                    p-TSA        --      --      --    0.4   0.4                                   Properties                                                                     Pencil hardness                                                                             3H-4H   4H      3H-4H H-2H  2H-3H                                 Knoop hardness                                                                              15.4    16.6    15.5  12.6  14                                    Reverse Impact                                                                              160     160     160   150   130                                   T-Bond       T2      T3      T4    T3    T5                                    Detergent Resistance,                                                          Blister Code, Hrs.                                                              48          10      10      10    10    F8                                     72          10      10      10    F9    F8                                    216          M8      M9      F9    D7    D6                                    384          M8      M/D9    D9    D4    --                                    Salt Spray Exposure                                                            Blister Code, 46 Hrs.                                                                       10      10      10    10    D8                                    Tape Pull, mm                                                                               0       0       0     0     4                                     168  hrs         10      10    10    D9    --                                       mm          0       0     0     2     5                                   300  hrs         10      10    10    --    --                                       mm          0       0     0     3     8                                   468  hrs         10      10    10    --    --                                       mm          0       0     0      4    10                                  1080 hrs         10      10    10    M1    --                                       mm          0       0     0     disint.                                                                              disint.                             1440 hrs         10      M /   10    --    --                                       mm          1       0     0     --    --                                  ______________________________________                                    

EXAMPLES 61-68

Titanium dioxide pigmented coating formulation are prepared by the general procedure described above and cured on steel panels, using 6-PC and methylolmelamine and methylolbenzoguanamine resins, the latter two as controls. The formulations used and the results obtained are set forth in Table 8 as follows:

                                      TABLE 8                                      __________________________________________________________________________     TiO.sub.2 - Pigmented Cured Coatings                                                          Example                                                                        61A 61  62  62A 63A 63                                          __________________________________________________________________________     Composition (parts by weight)                                                  JONCRYL ® 500.sup.a                                                                       --  --  75  75  --  --                                          AROPLAZ 1710 R60.sup.b                                                                        75  75  --  --  --  --                                          CYMEL ® 1473-5.sup.c                                                                      --  --  --  --  --  --                                          CARGILL 5775.sup.d                                                                            --  --  --  --  75  75                                          CYMEL ® 303.sup.c                                                                         25  --  --  --  15  --                                          CYMEL ® 1123.sup.c                                                                        --  --  --  25  --  --                                          CYMEL 6-PC.sup.e                                                                              --  25  25  --  --  25                                          EPON ® 1001.sup.f                                                                         --  --  --  --  10  --                                          T-12.sup.g     --  --  --  --  --  --                                          TBDAS.sup.h    --  1   1   --  --  1                                           p-TSA.sup.i    0.4 --  --  0.5 0.4 --                                          Cure Temp °C.                                                                          125 177 177 177 125 177                                         Properties                                                                     MEK Resist     200+                                                                               200+                                                                               200+                                                                               200+                                                                               200 200+                                        Cross-Hatch Adhesion                                                                          3   5   4   5   5   5                                           Knoop hardness 16.6                                                                               17.5                                                                               26  18  10.8                                                                               21                                          Reverse Impact 5   30-40                                                                              5   5   160 40                                          Film Thickness, mils                                                                          1.2 1.1 1.1 1.3 1.3 1.2                                         Detergent Resistance,                                                          Blister Code, Hrs.                                                              48            10  10  10  D8  10  D9                                           96            M/  D8  10  D6  M9  D9                                                         D8/9                                                            124            --  --  10  D9  M                                               148            --  --  10  YD6 VD9 VD9                                         192            D8  D6  10  D4  peeled                                                                             VD9                                         288            VD6 D4  D9  D2      VD4                                         336            --  --  D9  D2                                                  Salt Spray Exposure                                                            Blister Code, 46 Hrs.                                                                         10  10  10  D9  10  10                                          Tape Pull, mm  1   0   0   0   0   0.5                                         336                                                                               hrs         10  D8  10  D9  10  10                                             mm          2   1.5 0   3   1   0                                           800                                                                               hrs         10  D8  10  D9  10  10                                             mm          5   5   0   11  8   0                                           __________________________________________________________________________      .sup.a S. C. Johnson & Son, Inc., hydroxyfunctional polyacrylate;              .sup.b Spencer Kellog, Div. of Textron, Inc., siliconized polyester;           .sup.c American Cyanamid Company;                                              .sup.d Cargill Co.                                                             .sup.e Hexa(propylcarbamylmethyl)melamine (Ex. 1);                             .sup.f Shell Chemical Co.;                                                     .sup.g Dibutyltin dilaurate;                                                   .sup.h Tetrabutyldiacetoxy stannoxane;                                         .sup.i ptoluenesulfonic acid;                                                  NC = no change                                                           

The foregoing examples show that even without the epoxy resin (EPON® 1001) additive, the alkylcarbamate melamine systems outperform all state of the art melamine systems, which include the phenyl carbamate, alkoxymethyl and benzoguanamine systems in detergent resistance. The above-mentioned results are unexpected because alkyl urethanes on heating are known to be poorer leaving groups than the phenoxy blocked isocyanate system and therefore they would be expected to give somewhat inferior coating properties. The foregoing examples also show that the alkylcarbamylmethylated melamines of this invention also provide coatings with outstanding salt spray resistance in comparison with other melamine based systems.

It is generally the case also, that the alkylcarbamylmethylated melamines of this invention afford coatings with good color stability. While the phenyl analog gives off white to tan coatings on cure, the alkyl systems are unchanged. In addition, the phenylcarbamate based coatings on exposure to U.V. light change to a much darker color (tan to light brown), while the alkylcarbamate systems change only slightly to a light tan color. Finally, the data show that while outstanding resistance properties and color stability have been obtained with the alkylcarbamate melamines, other important and desirable coatings properties such as Knoop hardness, impact and solvent resistance (MEK rubs+200) have been maintained as is the case with conventional resins.

EXAMPLE 69

The product of Example 1 can be used as a binder for foundry sand. The binder as an acetone solution (e.g., 77 wt. %) containing 1 part/100 of TBDSA catalyst is kneaded with sand and the solvent is vaporized by heating. The amount of binder to sand is preferably 1-5.5 parts to 100 parts of sand. The coated sand is then filled into a core mold and heated at 200°-300° C. for 30 sec. to two minutes. A core having good strength and showing little tendency to give off gases having a strong smell (e.g., formaldehyde) will be obtained.

Instead of sand, glass powder and glass fiber can be substituted, in which case, thermally insulating shapes having good structural integrity will be obtained.

The above-mentioned patents and publications are incorporated herein by reference. Many variations of this invention will suggest themselves to those skilled in this art in light of the above, detailed description. Instead of using n-propylcarbamylmethylated- and methylcarbamylmethylated melamines as curing agents in the formulations of Tables 1-8, the corresponding alkyl (and mixed alkyl) carbamylmethylated melamine and melamine oligomers of Examples 3-16 can be used. Instead of tetrabutyldiacetoxy stannoxane and, dibutyltin dilaurate as cure catalysts, lead octoate, and stannous octoate can be used. Instead of hydroxyfunctional polyesters and polyacrylates, epoxy resins, such as the polyglycidylethers of bisphenol A and the reaction products thereof with amines and ammonia can be used. All such obvious modifications are within the full intended scope of the appended claims. 

We claim:
 1. An article of manufacture comprising a filler, a cure catalyst, and active hydrogen-containing material; and a triazine compound, wherein the triazine compound is as follows:A triazine compound selected from(i) a triaminotriazine compound of the formula C₃ N₆ (CH₂ OR)_(6-x) (CH₂ NHCOOR¹)_(x), or; (ii) a benzoguanamine compound of the formula C₃ N₅ (C₆ H₅) (CH₂ OR)_(4-y) (CH₂ NHCOOR¹)_(y), or; (iii) an oligomer of (i) or (ii), wherein the R groups are, independently, hydrogen or alkyl from 1 to 12 carbon atoms, the R¹ groups are, independently, alkyl from 1 to 12 carbon atoms, x is in the range of from about 2 to about 6, and y is in the range of from about 2 to about
 4. 2. An article as defined in claim 1 wherein the triaminotriazine compound (i) has x in the range of from about 2.8 to about
 6. 3. An article as defined in claim 1 wherein the benzoguanamine compound (ii) has y in the range of from about 2.2 to about
 4. 4. An article as defiend in claim 1 wherein for the triaminotriazine compound (i) the R groups are, independently, one to twelve carbon atom lower alkyl and the R¹ groups are, independently, methyl, ethyl, n-propyl, butyl, isopropyl, n-octyl, 2-ethylhexyl, or n-octadecyl.
 5. An article as defined in claim 1 wherein for the benzoguanamine compound (ii) the R groups are, independently, one to twelve carbon atoms lower alkyl and the R¹ groups are, independently, methyl, ethyl, n-propyl, butyl, isopropyl, n-octyl, 2-ethylhexyl, or n-octadecyl.
 6. An article as defined in claim 1 wherein the triazine compound is an oligomer of a triaminotriazine compound of the formula:

    C.sub.3 N.sub.6 (CH.sub.2 OR).sub.6-x CH.sub.2 NHCOOR.sup.1).sub.x

where the R is a C₁ to C₈ lower alkyl, and R₁ is methyl, ethyl, n-propyl, butyl, isopropyl, n-octyl, 2-ethylhexyl, n-octadecyl, and x is a number in the range of from about 2 to about
 6. 7. An article as defined in claim 1 wherein the triazine compound is an oligomer of a benzoguanamine compound of the formula:

    C.sub.3 N.sub.5 (C.sub.6 H.sub.5) (CH.sub.2 OR) .sub.4-y (CH.sub.2 NHCOOR.sup.1).sub.y

where the R is a C₁ to C₈ lower alkyl, and R¹ is methyl, ethyl, n-propyl, butyl, isopropyl, n-octyl, 2-ethylhexyl, n-octadecyl, and y is a number in the range of from about 2 to about
 4. 